Bis[μ-3-(2-hydroxyphenyl)propenoato]bis{aqua(4,4′-bipyridine)bis[3-(2-hydroxyphenyl)propenoato]yttrium(III)} 4,4′-bipyridine disolvate
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چکیده
منابع مشابه
Bis[μ-3-(2-hydroxyphenyl)propenoato]bis{aqua(4,4′-bipyridine)bis[3-(2-hydroxyphenyl)propenoato]yttrium(III)} 4,4′-bipyridine disolvate
The title compound, [Y(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2C(10)H(8)N(2), contains two eight-coordinated Y(III) ions, which are linked by two carboxyl-ate groups from two 2-hy-droxy-cinnamate anions, leading to a centrosymmetric dinuclear structure surrounded by solvent 4,4'-bipyridine mol-ecules. It forms a three-dimensional framework connected by extensive O-H⋯O and O-H⋯N hydrog...
متن کامل3-Aminobenzoic acid–4,4′-bipyridine (2/3)
The asymmetric unit of the title compound, 3C(10)H(8)N(2)·2C(7)H(7)NO(2), consists of three mol-ecules of 4,4'-bipyridine (bpy) and two mol-ecules of 3-amino-benzoic acid (bza). Two mol-ecules of bza and two mol-ecules of bpy are connected via O-H⋯N, N-H⋯N and N-H⋯O hydrogen bonds, forming forming infinite double-stranded zigzag chains along the c axis. The third mol-ecule of bpy is linked to t...
متن کامل4,4′-Bipyridine–2-hydroxypropane-1,2,3-tricarboxylic acid (3/2)
The combination of 2-hydroxy-propane-1,2,3-tricarboxylic acid (H(3)hypta, also called citric acid) and 4,4'-bipyridine (4,4'-bipy) in a 1:1.5 molar ratio leads to the formation of the title mol-ecular cocrystal, 1.5C(10)H(8)N(2)·C(6)H(8)O(7). The asymmetric unit contains one and a half 4,4'-bipy units, with one lying across a centre of inversion, and one H(3)hypta mol-ecule. The significant dif...
متن کامل4,4′-Bipyridine–3-nitrobenzoic acid (1/2)
The title compound, C(10)H(8)N(2)·2C(7)H(5)NO(4),was obtained unintentionally as the harvested product of the hydro-thermal reaction between Co(OAc)(2)·4H(2)O and 4,4'-bipyridine in the presence of 3-nitro-phthalic acid. In the reaction, 3-nitro-phthalic acid is transformed into 3-nitro-benzoic acid by an in situ deca-rboxylation reaction, in which the carboxyl-ate group is not deprotonated and...
متن کاملTetrakis[μ-3-(3-hydroxyphenyl)propenoato]bis{aqua(2,2′-bipyridine)[3-(3-hydroxyphenyl)propenoato]neodymium(III)} 2,2′-bipyridine disolvate dihydrate
The dinuclear title compound, [Nd(2)(C(9)H(7)O(3))(6)(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·2H(2)O, was synthesized under hydro-thermal conditions. The centrosymmetric complex consists of two nine-coordinated Nd(3+) cations, six 3-hy-droxy-cinnamate anions and two chelating 2,2'-bipyridine mol-ecules. The coordination geometry around the cations can be best described as distorted tricapped trigonal...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810044831